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Equilibrium

Question

The potential energy (U) of a diatomic molecule is a function dependent on  r (inter atomic distance) as
  U=αr10βr53
Where, α  and β  are positive constants. The equilibrium distance between two atoms will be  2αβab, where a=________
 

Moderate
Solution

U=ar10βr53

At equilibrium F=0

F=dUdr=10αr11+5βr600=10αr115βr610αr11=5βr6α=β2r52αβ=r5r=2αβ1/5 So, a=1 and b=5



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