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A sample of 0.1 g of water at l00°C and normal pressure.(1.013 x 105 Nm-2 )requires 54 cal of heat energy to convert to steam at 100°C. If the volume of the steam produced is 167.1 cc, the change in internal energy of the sample, is:

a
104.3 J
b
208.7 J
c
42.2 J
d
84.5 J

detailed solution

Correct option is B

Q=54 cal =54×4.18 joule=225.72 joule W=PVsteam-VwaterFor water 0.1 gram = 0.1 cc =0.013×105167.1×10-6-0.1×10-6joule =1.013×167×10-1=16.917 joule By FLOT ⇒  ∆U=Q-W=225.72-16.917=208.8 joule.

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