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X-rays emitted from a copper target and a molybdenum target are found to contain a line of wavelength 22.85 nm attributed to the Kα line of an impurity element. The Kα
lines of copper (Z = 29) and molybdenum (Z = 42) have wavelengths 15.42 nm and 7 .12 nm, respectively. The atomic number of the impurity element is

a
22
b
23
c
24
d
25

detailed solution

Correct option is C

Using Moseley's law, v1/2=a(z−b)cλ11/2=az1−b and cλ21/2=az2−bλ2λ112=az1−baz2−b⇒7.1215.4212=(29−b)(42−b)   (42−b)=1.47(29−b)⇒b=1.44λ1λ12=(z−1.44)z1−1.44 15.4222.8512(27.56)=z−1.44⇒z=24

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