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Strongest oxidant among the following is

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By Expert Faculty of Sri Chaitanya
a
B+3
b
Al+3
c
Ga+3
d
Tl+3

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detailed solution

Correct option is D

For Tl +1 oxidation state is more stable than +3 oxidation state .Therefore Tl+3 taking 2-electrons and converting to Tl+1.Hence Tl+3 acts as strong oxidising agent(electron gainer).Stability order of +3 oxidadtion state:B+3 > Al+3  > Ga+3  > In+3  >  Tl+3+III oxidation state (higher oxidation state) stability decreases from top to bottom in a group .Stability order of +1 oxidadtion state:B+1 < Al+1  < Ga+1  < In+1  <  Tl+1→ +I oxidation state (lower oxidation state) stability increases from top to bottom in a group .


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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