First slide
Atomic and physical properties
Question

The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

Moderate
Solution

F atom of BF3 shows  back bonding with electron deficient B-atom.

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