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For the tetrahedral complex [MnBr4]2-, the spin only magnetic moment value is: [At. no. of Mn= 25]

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By Expert Faculty of Sri Chaitanya
a
1.7
b
5.9
c
4.8
d
2.4

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detailed solution

Correct option is B

MnBr4−2Ox.State of Mnx+4−1  =  −2x=+2Mn(Z = 25) ……. [Ar]4s23d5  Mn+2 ……. [Ar]3d5Given that MnBr4−2  is a tetrahedral complex. ∴  No rearrangement occurs.Number of unpaired electrons(n) = 5μS=nn+2  B.MμS=55+2  B.MμS=5.9  B.MNote:–  In the formation of complex only vacant orbitals involve in hybridization.


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