First slide
Change in internal energy
Question

One mole of an ideal diatomic gas undergoes a transition from A to B along a path AB as shown in the figure      

The change in internal energy of the gas during the transition is

Moderate
Solution

At point A : PV = nRTA\Rightarrow 5 \times {10^3} \times 4 = nR{T_A}

20 \times {10^3} = nR{T_A}

At point B : PV = nRTB \Rightarrow 2 \times {10^3} \times 6 = nR{T_B}

12 \times {10^3} = nR{T_B}

\Delta U = n{C_V}\Delta T = n\frac{{5R}}{2}\left( {{T_B} - {T_A}} \right)

= \frac{5}{2}\left( {nR{T_B} - nR{T_A}} \right) = \frac{5}{2}\left( {12 \times {{10}^3} - 20 \times {{10}^3}} \right)

= \frac{5}{2}\left( { - 8 \times {{10}^3}} \right) = - 20 \times {10^3} = - 20KJ

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