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a

Calcium acetate 

b

Propanone 

c

Propane 

d

Ethanol

answer is B.

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Detailed Solution

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Acetylene on acidic hydrolysis in presence of HgSO4 gives aldehyde 

CHCHAcetylene HgSO4(aq.)H2SO4 CH3CHO Acetaldehyde  

Acetaldehyde when treated with Potassium dichromate in acidic condition gives carboxylic acid 

CH3CHO K2Cr2O7H2SO4 CH3COOHAcetic acid  

Acetic acid when treated with Calcium hydroxide it gives calcium derivative of carboxylic acid. 

CH3COOHCa(OH)2(CH3COO)2CaCalcium Acetate

 Calcium acetate on heating in air gives Propanone. 

(CH3COO)2CaCH3COCH3Propanone 

Hence, the correct answer is option (B) Propanone.

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