Q.

Consider the following reaction for the given image.

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The product formed in the reaction is :

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a

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b

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c

 

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d

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answer is C.

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Detailed Solution

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Reaction Steps:

Step 1: Oxymercuration

  • The reagent Hg(OAc) reacts with the double bond of the cyclic alkene, forming a mercurinium ion intermediate.
  • A water molecule attacks the more substituted carbon (following Markovnikov's rule), resulting in the addition of a hydroxyl group (-OH) to the more substituted carbon.

Step 2: Demercuration

  • The reagent NaBH reduces the organomercury intermediate, replacing the mercury group with a hydrogen atom.

Final Product:

The product is a 1,2-diol, meaning the molecule contains two hydroxyl groups (-OH) on adjacent carbons. The reaction follows anti-stereoselectivity, so the hydroxyl groups are added to opposite faces of the ring.

Detailed Product Structure:

  • The double bond in the original compound is converted into a single bond.
  • One hydroxyl group (-OH) remains at its original position (tertiary -OH).
  • A new hydroxyl group (-OH) is added to the carbon adjacent to the original -OH group.

Product:

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