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Q.

0.004 g of hydrocarbon on combustion liberates 0.011g of CO2 at STP.  The empirical formula of the hydrocarbon is _______

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a

C3H4

b

CH3

c

CH2

d

CH4

answer is A.

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Detailed Solution

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%  C=1244×wt.  of  CO2   liberatedwt. of  organic  compound  taken×100

%  C=1244×0.0110.004×100 = 75%

% H=100-% C=10075=25

C:H =7512  :  251=7512  ×  125=1:4

   EF=CH4

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0.004 g of hydrocarbon on combustion liberates 0.011g of CO2 at STP.  The empirical formula of the hydrocarbon is _______