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Q.

0.01 mol of a gaseous compound C2H2Ox was treated with 224 mL of O2 at NTP. After complete combustion the total volume of gases is 560 mL at NTP. On treatment with KOH solution the volume decreases to 112 mL. The value of x is:

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answer is 4.

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Detailed Solution

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Volume of CO2+ volume of remaining oxygen=560 mL Or Volume of remaining oxygen =112mL

C2H2Ox(g)+(5x2)O2(g)Δ2CO2(g)+H2O(l)
224 mL224 mL0-
0112 mL448 mL-

For used moles of O2:(5x2)×0.01=0.012 or x=4

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