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Q.

0.01 mole of iodoform reacts with Ag powder to produce a gas whose volume at NTP is

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a

224ml

b

112ml

c

336ml

d

1120 ml

answer is B.

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Detailed Solution

large CH{I_3} + 6Ag + {I_3}CH xrightarrow{Delta } 6AgI + CH equiv CH

(or)

large mathop {2CH{I_3}}limits_{begin{array}{*{20}{c}} {2moles} \ {0.01mole} end{array}} + 6Agxrightarrow{Delta }mathop {CH equiv CH}limits_{begin{array}{*{20}{c}} {22,400ml} \ {'X'ml} end{array}} + 6AgI

large X = 22400 times frac{0.01}{2}

X = 112ml

Volume of acetylene gas liberated at STP = 112ml

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