Q.

0.01 moles of a weak acid HA(Ka=2.0x10-6) is dissolved in 1.0 L of 0.1M  HCl solution. The degree dissociation of HA is________x10-5(Round off to the nearest integer). [Neglect volume change on adding HA. Assume degree of dissociation<<1].

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answer is 2.

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Detailed Solution

HA H++A

Initial               0.01         0         0
Dissociated      X           ___     ___ 
Produced        ___           x         x
Equilitrium      0.01-x      x        x
HCLH++Cl

0.1          0.1       0.1

Total[H+]=0.1+x0.1;x<<<0.1Ka=[H+][A][HA],22×106=0.1×Cα0.01α=2×106×102101×102=2×105=2

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