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Q.

0.037g of an alcohol, was added to CH3MgBr and the gas evolved measured 11.2mL at STP. The molecular mass of  ROH  will be ________(At STP gram molar volume=22.4lit)

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answer is 74.

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Detailed Solution

 ROH+CH3MgBr  CH4+Mg(OR)Br                                        1mole(or)22,400mL  at  STP
11.2mL  CH4   at STP is formed by 0.037g  ROH
  22,400 mL of   CH4  at STP will be formed by =0.03711.2×22400g  of  ROH =74g

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0.037g of an alcohol, was added to CH3MgBr and the gas evolved measured 11.2mL at STP. The molecular mass of  R−OH  will be ________(At STP gram molar volume=22.4lit)