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Q.

0.303g of organic compound was analyzed for nitrogen by Kjeldahl's method. The ammonia gas evolved was absorbed in 50ml of 0.05M H2SO4 . The excess acid required 25ml of 0.1M NaOH for neutralization. The percentage of nitrogen in the given compound is

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a

11.5

b

23

c

12.5

d

14.5

answer is A.

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Detailed Solution

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%N=1.4×NacidVacid-NNaOHVNaOHWt. of organic compound

         =1.450×0.1-25×0.10.303

          = 11.5%

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0.303g of organic compound was analyzed for nitrogen by Kjeldahl's method. The ammonia gas evolved was absorbed in 50ml of 0.05M H2SO4 . The excess acid required 25ml of 0.1M NaOH for neutralization. The percentage of nitrogen in the given compound is