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Q.

0.535gm of ethanol and acetaldehyde mixture when heated with Fehling's solution gave 1.2gm of red precipitate. If ‘x’ is the percentage of acetaldehyde in the mixture, then find the value of x=________ (nearest integer)
(At weight of Cu=63.5,O=16,C=12)
 

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answer is 69.

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Detailed Solution

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C2H5OH+CH3CHO=0.535gm

Let ‘a’ gm C2H5OH  and ‘b’ gm  CH3CHO  be present in mixture

 a+b=0.535

Now, mixture react with Fehling’s solution to give a red precipitate

Question Image

 

 

 

 143.6gmCu2O  is given by 44gm  CH3CHO

 1.2gmofCu2O   is given by ? 

=44×1.2143.6=0.368gmCH3CHO

b=0.368gm

%  of  %ofCH3CHO=0.3680.535×100=68.73%

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