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Q.

0.59g of the silver salt of an organic acid (mol.wt.210) on ignition gave 0.36g of pure silver. The basicity of the acid is [At.Wt of Ag=108 ]

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

Eq.wtofsilversaltEq.wtofpuresilver=MassofSilverSaltMassofpuresilver

E108=0.590.36

E=0.59×1080.36=177

Eq. Mass of organic acid = eq. mass of silver salt --- eq. mass of silver  + 1
 =177108+1=70
Basicity  =Massoforg.acidEq.Mass=21070=3

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