Q.

0.1 mol of CH3NH2 (Kb = 5 x 10-4) is mixed with 0.08 mol of HCI and diluted to 1 L. What will be the H+ concentration in the solution?

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a

8×102M

b

8×1011M

c

1.6×1011M

d

8×105M

answer is B.

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Detailed Solution

                  CH3NH2+H+ClCH3NH3+Cl Initial                  0.1      0.08               - Final                0.02          -              0.08 M
CH3NH2+H2OCH3NH3++OH Kb=CH3NH3+OHCH3NH2 5×104=(0.08)OH(0.02) OH=1.25×104M H+=KwOH=1×10141.25×104 =8×1011M

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