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Q.

0.1M solution of  KI reacts with excess of H2SO4and KIO3 solutions, according to equation 5I-+IO3-+6H+3I2+3H2O; which of the following statements is/are correct :

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a

200 mL of the  KI solution react with 0.004 mole KIO3

b

0.5 litre of the KI solution produced 0.005 mole of I2.

c

100 mL of the  KI solution reacts with 0.006 mole ofH2SO4.

d

Equivalent weight of KIO3 is equal to ( Molecular weight )5.
 

answer is A, B, D.

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Detailed Solution

0.1M solution of  KI reacts with excess of H2SO4and KIO3 solutions, according to equation : 5I-+IO3-+6H+3I2+3H2O

(a) 200 mL of the  KI solution react with 0.004 mole KIO3

=200×0.1

=  200  ×  0.15

(b) 100 mL of the  KI solution reacts with 0.006 mole ofH2SO4.

=100×0.1

100×0.165 nH2SO4

=100×0.1×61000×2×5=0.006

(d) Equivalent weight of KIO3 is equal to ( Molecular weight )5.
 

EKIO3=M5

Hence, the correct option is a, b and d.

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