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Q.

0.262 g of a substance gave, on combustion, 0.361g of CO2 and 0.147 g of H2O. What is the empirical formula of the substance

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a

CH2O

b

C2H6O2

c

C3H6O2

d

C3H6O

answer is A.

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Detailed Solution

% of carbon =1244×wt. of CO2wt. of organic compound×100=1244×0.3610.262×100=37.57

% of hydrogen

=218× wt. of H2O wt .of organic compound ×100=218×0.1470.262×100=6.23

% of oxygen =100(37.57+6.23)=56.2C=37.5712=3.13;H=6.231=6.23

O=56.216=3.51,   Empirical formula =CH2O

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