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Q.

0.262g of a substance gave, on combustion, 0.361g of CO2 and 0.147g of H2O. What is the empirical formula of the substance

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a

CH2O

b

C3H6O

c

C3H6O2

d

C2H6O2

answer is A.

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Detailed Solution

% of carbon 
=1244×Wt.of CO2 Wt.of organic compound ×100=1244×0.3610.262×100=37.57
% of hydrogen
=218× wt.of H2O wt.of organic compound ×100=218×0.1470.262×100=6.23
% of oxygen = 100 – (37.57+6.23) = 56.2
C=37.5712=3.13;H=6.231=6.23O=56.216=3.51
Empirical formula = CH2O

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