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Q.

0.262g of a substance gave on combustion 0.361g of CO2 and 0.147g Of H2O. What is the empirical formula of the substance

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a

C3H6O

b

CH2O

c

C2H6O2

 

d

C3H6O2

answer is A.

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Detailed Solution

44g of CO2 contains 12g of C. 

So, 0.361g of CO2 contains 12/ 44 x0.361 = 0.098g of C.

18g of H2O  contains 2g of H. 

So, 0.147g of H2O  contains 2/18 × 0.147 = 0.016g of H.

Amount of 'O' = 0.262  0.098  0.016 = 0.148 g of O

% of C = 0.098/ 0.262 x 100 = 37.4

% of H =0.016/ 0.262 x 100 = 6.1

% of O = 0.148 / 0.262 x 100 = 56.48

37.40/ 12 = 3.1

6.1/ 1= 6.1

56.48 / 16 = 3.5

by dividing with lowest value(3.1)

Hence, C : H : O = 1 : 2 : 1. So, the formula is CH2O.

Thus, the correct option is A.

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