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Q.

0.3 grams of platinum chloride of organic diacidic base left 0.09 grams of platinum on ignition,

the molecular weight of the organic base is  

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a

60

b

120

c

180

d

240

answer is B.

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Detailed Solution

2B+H4ptCl6B2H2ptCl6Δpt

Equivalent weight of B2H2ptCl6

= 2B + 410

0.32B+410=0.09195

 3.33 × 195 = 2B + 410

239.93 = 2B

B = 120

Molecular weight of base = 2 × E. Wt

                                                   = 2 × 120

                                                   = 240

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0.3 grams of platinum chloride of organic diacidic base left 0.09 grams of platinum on ignition,the molecular weight of the organic base is