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Q.

1 kg of water at 100°C is converted into steam at 100°C by boiling at atmospheric pressure. The volume of water changes from 1.00×103m3 as a liquid to 1.671m3 as steam. The change in internal energy of the system during the process will be ….. 
(Given latent heat of vaporization = 2257 kJ/kg. Atmospheric pressure = 1×105Pa )
 

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a

+2476 kJ

b

-2090 kJ

c

+2090 kJ

d

-2426 kJ

answer is C.

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Detailed Solution

detailed_solution_thumbnail

dQ=dU+PdV

mL=dU+PdV

dU=mLPdV =1×2257×103105×1670×103

dU=(2257167)×103=2090 kJ

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1 kg of water at 100°C is converted into steam at 100°C by boiling at atmospheric pressure. The volume of water changes from 1.00×10−3m3 as a liquid to 1.671m3 as steam. The change in internal energy of the system during the process will be ….. (Given latent heat of vaporization = 2257 kJ/kg. Atmospheric pressure = 1×105Pa )