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Q.

1 kg of water at 100°C  is converted into steam at 100°C by boiling at atmospheric pressure. The volume of water changes from 100×103m3 as a liquid to 1.671m3 as steam. The change in internal energy of the system during the process will be 
(Given, latent heat of vapourisation = 2257kJ/kg. Atmospheric pressure = 1×105  Pa)

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a

+2476 kJ

b

-2090 kJ

c

+2090 kJ

d

-2426 kJ

answer is C.

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Detailed Solution

dQ=du+PdvML=du+Pdvdu=MLPdvdu=1×22257×103           105×1670×103du=(2257167)×103du=2090KJ

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