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Q.

1 mL of unknown solution of H2SO4 is diluted 100 mL and then its 25 mL is titrated with 10 mL of 0.2 M NaOH. The excess acid required 10mL of 0.1s Ba(OH)2 solution. Find molarity of original H2SO4 solution.

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answer is 8.

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Detailed Solution

Here,

25 mI of H2SO4 contains milli equivalent

=10 X 0.2 + 10 X 0.1 X 2 = 4

 100ml contains =161×M×2=16 M=8

Thus, the required molarity is 8.

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1 mL of unknown solution of H2SO4 is diluted 100 mL and then its 25 mL is titrated with 10 mL of 0.2 M NaOH. The excess acid required 10mL of 0.1s Ba(OH)2 solution. Find molarity of original H2SO4 solution.