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Q.

1 mol N2 and 3 mol H2 are introduced in 8.21 litre container initially at 27C where no chemical reaction takes place. Select the correct statement(s).

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a

 Partial pressure of N2 is 12 atn

b

 Partial pressure of N2 is 3 atm

c

 Total pressure is 9 atm

d

If temperature is increased to 600 K  and NH3 formation takes place with 100 % yield then total pressure developed is 12 atm

answer is B, D.

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Detailed Solution

Pressure can be calculated as,

P=4×0.0821×3008.21=12atm

PN2=14×12, PH2=34×12

=3 atm   =9 atm

At  600 K  =  6 atm

N26+3H2182NH3

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