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Q.

1 mole each of A and B are mixed initially  in one lit closed flask at room temperature. If the equilibrium constant for the reaction AB is 0.5. Identify the correct statement from the following at equilibrium state?

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a

concentration of B is 13

b

concentration of A increases by 13

c

concentraion of B increases by 13

d

Concentration of A is 13

answer is A.

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Detailed Solution

all reaction components are present initially, initial reaction quotient is

Qc=1212=1

Qc > Kc equilibrium moves from right to left ( products to reactants)

A+x1 moleB-x1 mole

at equilibrium 

[A] = 1+x and [B] = 1-x

Kc[A][B] = 2(equilibrium is reversed its equlibrium constant is reciprocal)

1+x1-X=2

x =13

[A] = 1+13=43

[B] = 1-13=23

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