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Q.

1 mole of an ideal gas is contained in a cubical volume 'V'. ABCDEFGH at 300k. One face of the cube (EFGH) is made up of a material which totally absorbs any gas molecule incident on it. At a given time

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a

the pressure on EFGH would be zero.

b

the pressure on all the faces will be equal.

c

the pressure on EFGH would be double the pressure on ABCD

d

the pressure on EFGH would be half that on ABCD.

answer is D.

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Detailed Solution

For large number of molecules whose motions are completely at random, ux = uy = uz = u/√3

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where u = RMS velocity.

It m be the mass of each molecule, N = total number of molecules, Then

{P_{ABCD}} = {P_{yz}} = frac{{zm,,{u_y} times N}}{{{l^2} times frac{{2l}}{{4x}}}} = frac{{left( {mN} right)4_x^2}}{{{l^3}}}

= rho u_x^2 = frac{{rho {u^2}}}{3}

{P_{EFGH}} = {P_{xy}} = frac{{m,{u_z} times N}}{{{l^2} times 2l/{u_2}}} = frac{{left( {mN} right)u_z^2}}{{2{l^3}}}

= frac{1}{2}rho frac{{{u^2}}}{3}

therefore {P_{EFGH}} = frac{1}{2}{P_{ABCD}}.

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