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Q.

1 mole of equimolar mixture of ferric oxalate and ferrous oxalate will require x mole of KMnO4  in acidic medium for complete oxidation, then ‘x’ is….

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a

4.5 mole

b

0.9 mole

c

1.2 mole

d

0.5 mole

answer is B.

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Detailed Solution

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 3moleKMnO4=5moleFeC2O4
 6moleKMnO4=5moleFe2(C2O4)3
  1 mole equimolar mixture of FeC2O4and  Fe2(C2O4)3=0.9 moles of  KMnO4

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