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Q.

10 g of magnesium metal is burnt in air to give an equimolar mixture of magnesium oxide and magnesium nitride. The mixture thus obtained is treated with HCl.
The volume in L of 2 M HCl required to completely react with product mixture is_____.
[Atomic weights: Mg = 24, O = 16, N = 14]

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answer is 0.52.

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Detailed Solution

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$x \times 24 + 3 x \times 24 = 10 \Rightarrow x = 0.104 M g O + 2 H C l \overset{}{\to} M g C l_{2} + H_{2} O M g_{3} N_{2} + 8 H C l \overset{}{\to} 3 M g C l_{2} + 2 N H_{4} C l n_{H C l} = 10 x \Rightarrow 2 \times V = 1.04 \Rightarrow V = 0.52 L$

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