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Q.

10 moles of KMnO4 were consumed in each separate titration with oxalic acid, one in presence of H2SO4 and other in presence of HCl. Identify the correct option.

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a

25 moles of oxalic acid will be consumed in both cases

b

No oxalic acid will be consumed in case of HCl and less than 25 moles will be consumed in case of H2SO4

c

25 moles of oxalic acid will be consumed with H2SO4 and less than 25 moles of oxalic acid will be consumed with HCl.

d

25 moles of oxalic acid will be consumed with H2SO4 and with HCl more than 25 moles of oxalic acid will be consumed.

answer is D.

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Detailed Solution

25 moles of oxalic acid will be consumed with H2SO4 and less than 25 moles of oxalic acid will be consumed with HCl.

It can be proved with the following calculations;

5×10=2×nH2C2O4

nH2c2O4=25 [in presence of H2SO4.]

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