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Q.

100ml of 0.1M of Al2(SO4)3 is mixed with 100ml of 0.1M AlCl3. Molarity of Al+3 ion in the resulting solution is ____?

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a

0.15

b

0.01

c

0.005 

d

0.015

answer is B.

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Detailed Solution

Explanation

From Al2(SO4)3:

  • Moles of Al2(SO4)3:  Moles = Molarity × Volume = 0.1 M × 0.1 L = 0.01 moles
  • Each Al2(SO4)3 dissociates into 2 Al³⁺ ions:  Moles of Al³⁺ = 0.01 moles × 2 = 0.02 moles

From AlCl3:

Moles of AlCl3:

Moles = Molarity × Volume = 0.1 M × 0.1 L = 0.01 moles

Each AlCl3 dissociates into 1 Al³⁺ ion:

Moles of Al³⁺ = 0.01 moles × 1 = 0.01 moles

Total moles of Al³⁺ = 0.02 moles + 0.01 moles = 0.03 moles

Total volume = 100 mL + 100 mL = 200 mL = 0.2 L

Molarity = Total moles of Al³⁺ / Total volume (L)

Molarity = 0.03 moles / 0.2 L = 0.15 M

Final Answer:

Molarity of Al³⁺ ions = 0.15 M

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