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Q.

1.0 g of a non -electrolyte solute (molar mass250 g mol was dissolved in 51.2 g of benzene. If the freezing point depression constant, Kf of benzene is 5.12 K kg mol-, the freezing point of benzene will be lowered by : 

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a

0.2 K

b

0.4 K 

c

0.3 K

d

0.5 K

answer is B.

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Detailed Solution

Wt. of solute, w = 10 g, molar mass, M = 250

g mol,Kf=5.12 K kg mol,ΔTf=?,W=wt. of solvent = 51.2 g=51.21000 kg

ΔTf=Kf×m=KfWM×1W in kg=5.12K kg mol×1.0 g×1000250 g mol×51.2 kg=0.4 K.

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