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Q.

10ml of a solution of H2O2  labeled 10 volume strength just decolourise 100ml of potassium permanganate solution acidified with dilute  H2SO4  calculate the amount of potassium permanganate in the given solution.

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a

0.1563g

b

0.563g

c

5.63g

d

0.256g

answer is B.

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Detailed Solution

 2H2O22H2O+O2
 22400mL  of  O268g  H2O2
10mL  ofO2? 
 WH2O2=68×1022400g
1ml of  H2O2 contain  0.030334mol=0.00178 equivalent weight 10ml of  H2O2
Therefore 0.0178 equivalent will be present in 100ml of kmno4 solution 
Amount of kmno4 in given simple  =1585×0.0178  =0.563g

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