Q.

1×105 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this solution at 298K is _____________×108Sm1
Given: KSP(AgBr)=4.9×1013 at 298K
λ0Ag+=6×103Sm2mol1 λ0Br=8×103Sm2mol1 λ0NO3=7×103Sm2mol1

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answer is 13039.2.

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Detailed Solution

AgNO3Ag++NO3-

Ag+=NO3-=10-5 Br-=KspAg+ Br-=4.9×10-1310-5=4.9×10-8

Using the following formula:

m=k1000×M 6×10-2=kAg+1000×10-5 kAg+=6×10-5=6000×10-8 8×10-3=kBr-1000×4.9×10-8 kBr-=39.2×10-8 7×10-3=kNO3-1000×10-5 kNO3-=7×10-5=7000×10-8

Conductivity of solution:
6000+39.2+7000×10-8=13039.2×10-8 Sm-1

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