Q.

1.2 moles of SO3are allowed to dissociate in a 2 litre vessel the reaction is  2SO3(g)2SO2(g)+O2(g)and the concentration of oxygen at equilibrium is 0.1 mole per litre. The total number of moles at equilibrium will be

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a

2

b

1.6

c

0.8

d

1,4

answer is B.

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Detailed Solution

The balanced equation is

2SO3(g)2SO2(g)+O2(g)

Initial(mole):     1.2        0       0 

Change (mole): -2x        2x     x 

Equilib(mole): 1.2 -2x    2x     x

             =1.2-2×0.1 2×0.1   0.1

O2=0.1 mole.L_1

=nO2V in Litres=0.1 mol .L-1

=NO2=0.1×2

=0.2 mole

So total no. of moles = 0.8 +0.4 +0.2

=1.4

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