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Q.

120g of an organic compound that contains only carbon and hydrogen gives 330g of CO2 and 270 g of water on complete combustion. The percentage of carbon and hydrogen respectively are

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a

20 and 80

b

90 and 10

c

40 and 60

d

75 and 25

answer is C.

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Detailed Solution

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CxHy+x+y4O2xCO2+y2H2O

 Mole of CO2=33044=7.5

 Mole of H2O=27018=15

Mass of carbon = Mole of carbon × atomic-mass

= 7.5 X 12 = 90g

% of carbon =wt of CO2 X 1244X100wt of o.comp

% of hydrogen = 100 – 75 = 25%

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