Q.

120 g Mg was burnt in air to give a mixture of MgO and Mg3N2. The mixture is now dissolved in HCI to form MgCI2 and NH4CI, if 107 gram NH4CI is produced. Then the moles of MgCI2 formed is :

Mg+12O2MgO     ..(i)3Mg+N2Mg3N2          ...(ii)MgO+2HClMgCl2+H2O          ...(iii)Mg3N2+8HCl2NH4Cl+3MgCl2         ..(iv)

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a

3 moles

b

10 moles

c

6 moles

d

5 moles

answer is C.

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Detailed Solution

The moles of MgCI2 formed is 5 moles

nMg=12024=5, nNH4Cl=10753.5=2 nMgCl2=   3         +         (53)         from eq. (iv)    from eq. (iii) 

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