Q.

1.22g of an organic acid is separately dissolved in 100 g of benzene Kb=2.6 K kg mol-1 and 100 g of acetone Kb=1.7 K kgmol -1. He acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by 0.17°C. The increase in boiling point of solution in benzene in C  0 is  x ×10-2. The value of x is  ______ [Atomic mass C=12.0H=1.0,O=16.0]

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answer is 13.

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Detailed Solution

With benzene as solvent, i=1/2

ΔTb=iKbm
ΔTb=12×2.6×1.22/Mw100/1000

With Acetone as solvent, i=1
ΔTb=iKbm
0.17=1×1.7×1.22/Mw100/1000

(1) / (2)
ΔTb0.17=12×2.6+1.22/Mw100/10001×1.7×1.22/Mw100/1000
ΔTb=0.262
ΔTb=13×10-2
x=13

Hence, the correct answer 13.

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