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Q.

12S8(g)+6O2(9)4SO3;ΔH°=-1590KJ The standard enthalpy of formation of SO3 is

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a

-3.975KJmol-1

b

-1590KJmol-1

c

-397.5KJmol-1

answer is B.

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Detailed Solution

ΔHf=ΔHf (products) -ΔHf( reactants )

 Given ΔHf=-1590KJ

 The reactants are in elemental form and hence the enthalpy of formation is zero

 By substituting the values in the above equation

 -1590=4×ΔHfSO3-0 =4 moles of sulphur trioxide are formed

 HfSO3=-15904=-397.5

Hence the correct option is (B).

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