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Q.

135 g of water is electrolysed during an experiment. If the efficiency of current is 75% then select the correct statement
 

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a

168 L of O2 (g) will be evolved at anode at STP

b

 84 L of H2(g) will be evolved at cathode at STP

c

15 F electricity will be consumed

d

20 F electricity will be consumed

answer is D.

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Detailed Solution

H2H212O2

1 mol of H2​O forms 1 mol of H2​ and 12 mol of O2

So, moles of H2O = 13518 = 7.5 mol, moles of H2 is also 7.5 mol and moles of O2 is 7.52 mol.

If one mole of water requires 2 F of electrons, then Faraday requires for 7.5 mol of water:

Amount of Faraday=2 F1 mol×7.5 mol=15 F

But efficiency is given as 75%, therefore the total electricity consumed (x) is:

x×75100=15 F x=20 F

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