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Q.

13th group elements show +1 and +3 oxidation states. 14th group elements show +2 and +4 oxidation states. Incorrect order about the stability of their oxidation states is

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a

Sn+4>Sn+2

b

Pb+2>Pb+4

c

Al+3>Al+

d

Tl+3>Tl+

answer is D.

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Detailed Solution

Thallium due to inert pair effect is more stable in “+1” state;

Tl and Pb show inert pair effect. They are stable in their lower oxidation state;

Other than Tl and Pb remaining elements are stable in their group number oxidation state ;

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