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Q.

15 mL of aqueous solution of Fe2+ in acidic medium completely reacted with 20 mL of 0.03M aqueous Cr2O7 2-. The molarity of the Fe2+ solution is 10-2M. (Round off to the Nearest Integer).

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answer is 24.

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Detailed Solution

Meq of Fe2+=Meq of Cr2O72-

M×15×n- factor =0.03×20×n- factor

In the reaction, Fe2+ is oxidised to Fe3+ hence, the n-factor is 1.

Also, Cr2O72- is reduced to 2Cr3+. Thus, 6 electrons are involved. Hence, its n-factor is 6.

Molarity =0.24M24×10-2M

Hence the correct answer is 24.

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