Q.

18 g of glucose, C6H12O6 (Molar mass – 180 g mol-1) is dissolved in 1 kg of water in a sauce pan. At what temperature will this solution boil? (Kb for water = 0.52 K kg mol-1, boiling point of pure water = 373.15 K)

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Detailed Solution

We know that : Elevation of boiling point ΔTb
 WBMB ×100× Kbwt. of solvent.
Given: WB = 18 g 
MB = Formula of glucose is C6H12O6 
= 6 × 12 + 12 + 6 × 16 = 180 
Wt. of solvent = 1 kg or 1000 g, 
Kb = 0.52 K kg mol-1 
Hence, ΔTb = 18g180×1000×0.521000g = 0.52 K 
∴B.P of the solution = 373.15 + 0.052 
= 373.202 K

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