Q.

18 mL of mixture of acetic acid and sodium acetate required 6 mL of 0.1 M NaOH for neutralization of the acid and 12 mL of 0.1 M HCl for reaction with for reaction with salt, separately. If pKa of the acid is 4. 75, what is the pH of the mixture? [log2=0.3]

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a

5.05

b

4. 75

c

4.6

d

4.5

answer is A.

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Detailed Solution

 meq of AcONa=12×0.1=1.2  meq of  AcOH =0.6

pH=4.75+log1.20.6=5.05

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