Q.

18 g of Glucose is dissolved in 90 g of water. The relative lowering of vapour pressure of solution is

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a

18108

b

5051

c

15.1

d

151

answer is A.

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Detailed Solution

We know that, from Raoult's law for non-volatile solute

p°-psp°=n2n1+n2

 p°-pSp°=n2n1+n2=w2m2W1m1+w2m2

where,

 w2= mass of solute(glucose)   

m2= molar mass of glucose 

W1= mass of solvent(water) 

m1= molar mass of water

Given that, w2=18g,W1=90g

Molar mass of glucose(m2)=

C6H12O6=12×6+12×1+6×16=180

Molar mass of water(m1)=

H2O=2+16=18

Now, putting the values, we get

p°-pSp°=181809018+18180=18180900180+18180=18918=151

Therefore, Relative lowering of vapour pressure is 151.

Hence, option(a) is correct.

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