Q.

ν1 and ν2 are the frequencies of  limiting line  for Lyman and Balmer series. Which relation is correct for frequency ν3 of 1st line of Lyman series?

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a

v3 =v1+v2

b

v3 = v1 x v2

c

v3=v1-v2

d

v3=v1v2

answer is B.

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Detailed Solution

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 Given, frequencies of  limiting line of Lyman and Balmar series are as v1 and v2 respectively

Thusv1=hcv¯1=hcRH112-12 = hcRH

v2=hcv¯2=hcRH122-12=hcRH4

for the first line in Lyman series

v3=hcv¯3=hcRH112-122=3hcRH4

Thus v3=v1-v2

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