Q.

1cm3 of water at its boiling point 100°C becomes steam with a volume of 1671cm3. If the atmospheric pressure =1.013 x 105 N/m2 & the mechanical equivalent of heat = 4.19 J calorie, then the energy spent in this process in overcoming intermolecular forces is nearly

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a

zero

b

500 cal

c

40 cal

d

540 cal

answer is C.

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Detailed Solution

The energy spent in overcoming intermolecular forces is called change in internal energy.

Heat given to system = Latent heat = mL = 1540=540 cal

ΔQ=ΔU+ΔWΔU=ΔQΔW=540PV2-V1J=5401.013×105×(16711)×1064.19=54040.4=500 calories (approx)

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