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Q.

1g of charcoal adsorbs 100 mL 0.5 M CH3COOH to form a monolayer, and thereby the molarity of CH3COOH reduces to 0.49. Calculate the surface area of the charcoal covered by each molecule of acetic acid. Surface area of charcoal =3.01×102m2/g

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a

4×1020m2

b

0.5×1019m2

c

5×1019m2

d

0.5×1010m2

answer is D.

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Detailed Solution

Amount of CH3COOH adsorbed on lg of charcoal =0.50.49molL1×1000mL1000mL/L=1×103mol
So, No. of CH3COOH molecules in 1 x 10-3 mol of acetic acid =6.02×1023mol1×103mol=6.02×1020
Area occupied by one CH3COOH molecule = 3.01×102m26.02×1020=5×1019m2
Thus the surface area of the charcoal covered by each CH3COOH molecule is 5 x 10-19 m2.

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